题干

下图装置(Ⅰ)为一种可充电锂离子电池的示意图,该电池充、放电的化学方程式为:Li4Ti5O12+3Li  Li7Ti5 O12 。装置(Ⅱ)为电解池的示意图。当闭合K1,断开K2时,Fe电极附近溶液先变红。下列说法正确的是(   )

A:闭合K1,断开K2时,若将Fe电极和石墨电极互换,装置(Ⅱ)中发生的总反应为:2NaCl+2H2O __ 2NaOH+Cl2↑+H2

B:闭合K1,断开K2时,当0.1 mol Li从A极区迁移到B极区,理论上Fe电极上产生的气体体积为1.12 L(标准状况下)

C:取下锂离子电池充电,电极A为阳极,发生还氧化反应,电极上发生的电极反应式为:Li7Ti5 O12 -3e= Li4Ti5 O12+3 Li+

D:若开始时,断开K1,闭合K2,一段时间后,石墨电极附近显红色,则该电极反应为:2H++2e-=H2

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B

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