题干

CO2是引起“温室效应”的主要物质,节能减排,高效利用化石能源,控制CO2排放,探索CO的循环利用是保护环境,促进经济科持续发展的重要举措.
(1)在一定温度下,向2L固定容积的密闭容器中通入2mol CO2,3mol H2,发生反应为:CO2(g)+3H2(g)⇌CH3OH(g)+H2O(g)△H=﹣490KI/mol
测得CO2(g)和CH3OH(g)的浓度随时间变化如图1所示.
①能说明该反应已达到平衡状态的是____ 
A.CO2(g)体积分数在混合气体中保持不变
B.单位时间内有1.2mol H﹣H断裂,同时有0.8mol O﹣H键生成
C.混合气体的密度不随时间变化
D.当体系中c(H2O):c(CH3OH)=l:l,且保持不变
②下列措施能使
n
C
H
3
O
H
n
C
O
2
增大的是____ 
A.升高温度   B.恒温恒容充入Hc(g)   C.使H2O(g)变成H2O(l)
D.恒温恒容下,再充入2mol CO2,3mol H2
③计算该温度下此反应的平衡常数K=____ ;若使K=1应采取的措施是____  
A.增大压强B.恒压加入一定量H2C.恒容通入CO2D.降低温度E.升高温度
(2)如图2所示:用某甲醇燃料电池作电源电解饱和食盐水.
①写出电极N发生的反应式:____  
②若食盐水体积为300Ml,电解过程溶液体积变化忽略不计,常温下测得pH=13时,理论上消耗甲醇质量为____ g.
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答案(点此获取答案解析)

A,CD,0.2,D,O2+4e+4H+=2H2O,0.16

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