题干

(1)2mol O3和 3mol O2的质量之比为  ____ ,分子数之比为  ____ ,同温同压下的密度之比为  ____ ,含氧原子数之比  ____ ,体积之比为  ____ .

(2)在标准状况下,由CO和CO2组成的混合气体6.72L,质量为11.6g.此混合物中CO的物质的量为   ____,混合气体的平均相对分子质量为  ____ .

(3)甲醇是一种重要的化工原料,在生产中有着重要的应用,工业上用甲烷氧化法合成甲醇的反应有:

(i)CH4(g)+CO2(g)⇌2CO(g)+2H2(g)△H1=+247.3kJ•mol1

(ii)CO(g)+2H2(g)⇌CH3OH (g)△H2=﹣90.1kJ•mol1

(iii)2CO(g)+O2(g)⇌2CO2(g) )△H3=﹣566.0kJ•mol1

用CH4和02直接制备甲醇蒸气的热化学方程式为  ____

(4)甲醇/空气﹣KOH燃料电池广泛应用于笔记本电脑储能供能装置,电池工作原理如图所示.

 ①写出负极反应方程式  ____

 ②电池工作过程中电解质溶液pH ____(填“升高”、“降低”、“不变”)

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答案(点此获取答案解析)

1\uff1a1,2\uff1a3,3\uff1a2,1\uff1a1,2\uff1a3,0.1mol,38.7,2CH4\uff08g\uff09+O2\uff08g\uff09\u21cc2CH3OH\uff08g\uff09\u25b3H=\ufe63251.61kJ/mol,CH3OH\ufe636e\ufe63+8OH\ufe63

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