题干

食盐中含有一定量的镁、铁等杂质,加碘盐中碘的损失主要是由于杂质、水分、空气中的氧气以及光照、受热而引起的.已知:

氧化性:IO3->Fe3+>I2;还原性:S2O32->I

3I2+6OH═IO3-+5I+3H2O;KI+I2⇌KI3

(1)某学习小组对加碘盐进行如下实验:取一定量某加碘盐(可能含有KIO3、KI、Mg2+、Fe3+),用适量蒸馏水溶解,并加稀盐酸酸化,将所得溶液分为3份.第一份试液中滴加KSCN溶液后显红色;第二份试液中加足量KI固体,溶液显淡黄色,用CCl4萃取,下层溶液显紫红色;第三份试液中加入适量KIO3固体后,滴加淀粉试剂,溶液不变色.

①加KSCN溶液显红色,该红色物质是____ (用化学式表示);CCl4中显紫红色的物质是 ____  (用电子式表示).

②第二份试液中加入足量KI固体后,反应的离子方程式为____ 、____ .

(2)KI作为加碘剂的食盐在保存过程中,由于空气中氧气的作用,容易引起碘的损失.写出潮湿环境下KI与氧气反应的化学方程式: ____ .将I2溶于KI溶液,在低温条件下,可制得KI3•H2O.该物质作为食盐加碘剂是否合适?____ (填“是”或“否”),并说明理由____ .

(3)为了提高加碘盐(添加KI)的稳定性,可加稳定剂减少碘的损失.下列物质中有可能作为稳定剂的是____ .

A.Na2S2O3B.AlCl3C.Na2CO3D.NaNO2


上一题 下一题 0.0难度 选择题 更新时间:2019-03-21 09:25:40

答案(点此获取答案解析)

Fe\uff08SCN\uff093,,IO3\ufe63+5I\ufe63+6H+\u25503I2+3H2O,2Fe3++2I\ufe63\u25502Fe2++I2,4KI+O2+2H2

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