题干

一定温度时,向容积为2L的密闭容器中充入一定量的SO2和O2,发生反应,2SO2(g)+O2(g)⇌2SO3(g).反应过程中测定的部分数据见下表(表中t1<t2),下列说法正确的是(   )

反应时间/min

n(SO2)/mol

n(O2)/mol

0

0.10

0.060

t1

0.012

t2

0.016

A:反应在0~t1 min内的平均速率为v(SO3)=0.088/t1 mol•L﹣1•min﹣1

B:保持其他条件不变,起始时向容器中充入0.10 mol SO3和0.010 mol O2,到达平衡时,n(SO2)=0.012 mol

C:保持其他条件不变,升高温度,平衡时c(SO2)=0.007 0 mol•L﹣1,则反应的△H>0

D:相同温度下,起始时向容器中充入0.050 mol SO2和0.030 mol O2,达到平衡时SO2转化率大于88%

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D

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