题干

能源短缺是人类社会面临的重大问题.甲醇是一种可再生能源,具有广泛的开发和应用前景.

(1)工业上一般采用下列两种反应合成甲醇:

反应Ⅰ:CO(g)+2H2(g)⇌CH3OH(g)△H1

反应Ⅱ:CO2(g)+3H2(g)⇌CH3OH(g)+H2O(g)△H2

①上述反应符合“原子经济”原则的是____ (填“I”或“Ⅱ”).

②下表所列数据是反应I在不同温度下的化学平衡常数(K).

温度

250℃

300℃

350℃

K

2.041

0.270

0.012

由表中数据判断△H1____ 0 (填“>”、“=”或“<”).

③某温度下,将2mol CO和6mol H2充入2L的密闭容器中,充分反应,达到平衡后,测得c(CO)=0.2mol/L,则CO的转化率为____ ,此时的温度为____ (从上表中选择).

(2)已知在常温常压下:

①2CH3OH(l)+3O2(g)=2CO2(g)+4H2O(g)△H=﹣1275.6kJ/mol

②2CO(g)+O2(g)=2CO2(g)△H=﹣566.0kJ/mol

③H2O(g)=H2O(l)△H=﹣44.0kJ/mol

写出甲醇不完全燃烧生成一氧化碳和液态水的热化学方程式:____ 

(3)某实验小组依据甲醇燃烧的反应原理,设计如图所示的电池装置.

①该电池正极的电极反应为____ .

②工作一段时间后,测得溶液的pH减小,该电池总反应的化学方程式为____ 

上一题 下一题 0.0难度 选择题 更新时间:2017-07-29 09:22:42

答案(点此获取答案解析)

\u2160,\uff1c,80%,250\u2103,CH3OH\uff08l\uff09+O2\uff08g\uff09=CO\uff08g\uff09+2H2O\uff08l\uff09\u25b3H=\ufe63442.8kJ\u2215mol,O2+2H2O+4e\ufe63=4OH\ufe63,2CH

同类题3

阅读下面短文,掌握其大意,然后从各题所给的A、B、C和D项中,选出最佳选项。

       When the weather turns warm, everyone wants to be in or around the water. Hanging out at the pool or the beach on a hot day is a great way to beat the heat.

       Most people don't think much about water 1—but they should. For people between the ages of 5 and 24, drowning is the second  2 cause of accidental death.

       It doesn't have to be that way,  3.By knowing how to stay safe and following a few simple guidelines, most water related accidents can be  4.

       It's a good idea to swim only in places that are watched over by a lifeguard. 5  can predict changing ocean currents, sudden storms, or other  6  dangers. In the event that something does go wrong, lifeguards are trained in  7  techniques.

       Swimming in an  8 body of water(like a river, lake, or ocean) is different from swimming in a pool. You need more  9 to handle the currents and other changing conditions in the open water.

       If you do find yourself  10  in a current, don't panic and don't fight the current. Try to swim parallel(平行) to the shore until you are able to  11  the current, which is usually a narrow channel of water.  12  try to make your way back to shore as you do so. If you're  13  to swim away from the current, stay calm and 14 with the current. The current will usually  15,then you can swim to shore.

       16  a very good swimmer who tries to swim against a strong current will get worn out. If you're going to  17  in open water, better take lessons that provide you with tips on  18  unexpected dangers.

       Some areas with extremely strong currents are  19 limits when it comes to swimming. Do your research so you know 20  not to swim, and pay attention to any warning signs posted in the area.