题干

淮南是我国重要的煤炭生产基地,通过煤的气化和液化,能使煤炭得以更广泛的应用.

Ⅰ.工业上先将煤转化为CO,再利用CO和水蒸气反应制H2时,存在以下平衡:CO(g)+H2O(g)⇌CO2(g)+H2(g)

(1)向2L恒容密闭容器中充入CO和H2O(g),800℃时测得部分数据如下表.

t/min

0

1

2

3

4

n(H2O)/mol

1.20

1.04

0.90

0.70

0.70

n(CO)/mol

0.80

0.64

0.50

0.30

0.30

则从反应开始到2min时,用H2表示的反应速率为____;该温度下反应的平衡常数K=____(小数点后保留1位有效数字).

(2)相同条件下,向2L恒容密闭容器中充入1molCO、3mol H2O(g)、2molCO2(g)、2mo1H2(g),此时v正____v逆(填“>”“<”或“=”).

Ⅱ.已知CO(g)、H2(g)、CH3OH(l)的燃烧热分别为283kJ•mol﹣1、286kJ•mol﹣1、726 kJ•mol﹣1.

(3)利用CO、H2合成液态甲醇的热化学方程式为____ 

(4)依据化学反应原理,分析升高温度对制备甲醇反应的影响____ 

Ⅲ.为摆脱对石油的过度依赖,科研人员将煤液化制备汽油,并设计了汽油燃料电池,电池工作原理如右图所示:一个电极通入氧气,另一电极通入汽油蒸气,电解质是掺杂了Y2O3的ZrO2晶体,它在高温下能传导O2﹣.

(5)以己烷(C6H14)代表汽油,写出该电池工作时的负极反应方程式____ 

(6)已知一个电子的电量是1.602×10﹣19C,用该电池电解饱和食盐水,当电路中通过1.929×105C的电量时,生成标况下氢气的体积为____ L.

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答案(点此获取答案解析)

0.075mol\u2022\u2022L\ufe631\u2022min\ufe631\u3000,1.2,\uff1c,CO\uff08g\uff09+2H2\uff08g\uff09=CH3OH\uff08l\uff09\u25b3H=\ufe63129kJ\u2022mol\ufe631\u3000,\u5347\u9ad8\u6e29\u5ea6\u4f7f

同类题2

任务型阅读

    Do you know what a big dream is? Does a big dream show one's future? Or, is a big dream something that provides only entertainment? Children dream big dreams, but there are three barriers to realizing dreams____

The self

    Immediately following the birth of a big dream, a negative self-talk takes over and gives all the reasons why it cannot happen. This voice inside of people is the ego(自我).It's there for protecting and should be listened to. Sometimes it is right, but more often it is wrong____ That's why only a handful of people make their dream come true

Family and friends

    Family and friends are a lot the ego.____ so they will often list all the reasons why the big dreams won't come true. Sometimes, family and friends destroy dreams of those they love most, out of their own fear of those left behind.

____

    If one gets past the first two barriers, one has to face the world. It is the last and the most terrible barrier. In the past, big dreamers were locked up and sometimes even killed when they were shown to the world. Fortunately, in most of the world today, big dreamers just get laughed at ____When children feel confident and then try their best, they will be ready to accept any failure. The truth is that every great dreamer whose dreams have never seen the light of success knows failure well. They simply fail until they succeed

A. The world

B. The future

C. Most people are influenced by it

D. They want to protect those they love

E. And their big dream is to be a rock star or a famous artist

F. They often kill them before they ever have a chance to grow

G. The way to realize a big dream is with confidence and action