题干

实验室以正丁醇、溴化钠、硫酸为原料制备正溴丁烷的反应如下:

NaBr+H2SO4═HBr+NaHSO4

CH3CH2CH2CH2OH+HBr →△  CH3CH2CH2CH2Br+H2O

在圆底烧瓶中加入原料,充分振荡后加入几粒沸石,安装装置Ⅰ.加热至沸腾,反应约40min.待反应液冷却后,改装为装置Ⅱ,蒸出粗产品.部分物理性质列表如下:

物质

正丁醇

正溴丁烷

沸点/℃

117.2

101.6

熔点/℃

﹣89.12

﹣112.4

密度/g•cm﹣3

0.8098

1.2758

溶解性

微溶于水,溶于浓硫酸

不溶于水和浓硫酸

将所得粗产品倒入分液漏斗中,先用10mL水洗涤,除去大部分水溶性杂质,然后依次用5mL浓硫酸、10mL水、10mL饱和NaHCO3溶液、10mL水洗涤.分离出有机层,加入无水氯化钙固体,静置1h,过滤除去氯化钙,再常压蒸馏收集99~103℃馏分.

回答下列问题:

上一题 下一题 0.0难度 选择题 更新时间:2016-06-30 04:36:00

答案(点此获取答案解析)

同类题1

“建国60年,前30年高举旗帜,中国软实力高于硬实力:后30年韬光养晦,中国
的硬实力高于软实力。”后30年中国“硬实力”增强的主要原因是:

同类题2

铁与稀盐酸(HCl)反应生成氢气和氯化亚铁(FeCl2)。将7克铁粉与足量的盐酸反应,产生的氢气在标准状况下的体积是多少升?(在标准状况下,氢气的密度为0.0899g/L,计算结果精确到0.01)

同类题3

阅读理解

    During the day we work and play; at night we sleep. Our bodies rest while we sleep. In the morning we are ready to work and play again. While we are asleep, our bodies grow most. Children who are tired usually need more sleep. We can get our lessons better and we feel better too when we have a good rest. Boys and girls who are eight or nine years old need ten hours of sleep every night. Our bodies need plenty of air when we sleep. If we do not get enough fresh air we'll feel tired when we wake up. While in bed we must not cover our heads. If we do, our lungs(肺)will not get enough fresh air. If we open our windows at night we can have plenty of fresh air. Cool air is better than warm air. Boys and girls who want to grow and be strong must get plenty of sleep.

同类题4

造句。

①只要……就……

②虽然……但是……

同类题5

下列关于溶液和胶体的叙述中,正确的是(  )
小学学科试题库
初中学科试题库
高中学科试题库