题干

合成氨对化学工业和国防工业具有重要意义.

(1)向合成塔中按1:4的物质的量之比充入N2、H2进行氨的合成,图A为T℃时平衡混合物中氨气的体积分数与压强(P)的关系图.

①写出工业上合成氨的化学方程式____ 

②图A中氨气的体积分数为15.00%时,H2的转化率=____ 

③图B中T=500℃,温度为450℃对应的曲线是____ (选填字母“a“或“b”),选择的理由是____

④由图象知,增大压强可提高原料的利用率,从生产实际考虑增大压强需解决的问题是____ (写出一条即可).

(2)合成氨所需的氢气可由甲烷与水反应制得,反应的热化学方程式为:

CH4(g)+H2OCO(g)+3H2(g);△H=+QkJ/mol(Q>0)

(3)一定温度下,在2L容器中发生上述反应,各物质的物质的量变化如下表

时间/min

CH4(mol)

H20( mol)

CO (mol)

H2 (mol)

0

0.40

1.00

0

0

5

X1

X2

X3

0.60

7

Y1

Y2

0.20

Y3

10

0.21

0.81

0.19

0.62

①分析表中数据,判断5〜7min之间反应是否处于平衡状态____ (填“是”或“否”),

前5min平均反应速率v(CH4)=____ 

②反应在7~10min之间,CO的物质的量减少的原因可能是____ (填字母).

a·减少CH4      b·降低温度c·增大压强d·充入H2

③若保持温度不变,向1L容器中起始充入0.15mol CH4.0.45mol H2O.____ mol CO、____ mol H2,达到平衡时CH4的体积百分含量与第一次投料相同.

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答案(点此获取答案解析)

N2+3H22NH3,24.45%,b,\u5408\u6210\u6c28\u7684\u6b63\u53cd\u5e94\u662f\u653e\u70ed\u53cd\u5e94\uff0c\u6839\u636e\u52d2\u590f\u7279\u5217\u539f\u7406\uff0c\u5176\u4ed6\u6761\u4ef6\u4e0d\u53d8\uff0c\u964d\u4f4e\u6e2

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