题干

醇脱水是合成烯烃的常用方法,实验室合成环己烯的反应和实验装置如图:

→△浓硫酸 +H2O,

可能用到的有关数据如表:

相对分子质量

密度/(g•cm﹣3)

沸点/℃

溶解性

环己醇

100

0.961 8

161

微溶于水

环己烯

82

0.810 2

83

难溶于水

合成反应:

在a中加入20g环己醇和2小片碎瓷片,冷却搅动下慢慢加入1mL浓H2SO4,b中通入冷却水后,开始缓慢加热a,控制馏出物的温度不超过90℃

分离提纯:

反应粗产物倒入分液漏斗中分别用少量5%碳酸钠溶液和水洗涤,分离后加入无水氯化钙颗粒,静置一段时间后弃去氯化钙,最终通过蒸馏得到纯净环己烯12g.

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上一题 下一题 0.0难度 选择题 更新时间:2019-12-06 04:45:44

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