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下面是实验室用双氧水和二氧化锰制取氧气及探究其化学性质的装置图,请回答:

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同类题1

已知:反应I:4NH3(g)+6NO(g)⇌5N2(g)+6H2O(l)△H1

反应Ⅱ:2NO(g)+O2(g)⇌2NO2(g)△H2(且|△H1|=2|△H2|)

反应Ⅲ:4NH3(g)+6NO2(g)⇌5N2(g)+3O2(g)+6H2O(l)△H 3

反应I和反应Ⅱ在不同温度时的平衡常数及其大小关系如下表

温度/K

反应I

反应II

已知:

K2>K1 >K2′>K1

298

K1

K2

398

K1

K2

(1)△H3=____ (用△H1、△H2的代数式表示);推测反应Ⅲ是____ 反应(填“吸热”或“放热”)

(2)相同条件下,反应I:4NH3(g)+6NO(g)⇌5N2(g)+6H2O(l)在2L密闭容器内,选用不同的催化剂,反应产生N2的量随时间变化如图所示.

①计算0~4分钟在A催化剂作用下,反应速率VNO=____ .

②下列说法不正确的是____ .

A.单位时间内H﹣O键与N﹣H键断裂的数目相等时,说明反应已经达到平衡

B.若在恒容绝热的密闭容器中发生反应,当K值不变时,说明反应已经达到平衡

C.该反应的活化能大小顺序是:Ea(A)>Ea(B)>Ea(C)

D.增大压强能使反应速率加快,是因为增加了活化分子百分数

(3)一定条件下,反应II达到平衡时体系中n(NO):n(O2):n(NO2)=2:1:2.

①保持恒温恒容,再充入NO2气体,NO2体积分数____ (填“变大”、“变小”或“不变”)

②关于平衡体系反应Ⅱ:2NO(g)+O2(g)⇌2NO2(g);△H2说法正确的是____ .

A、该反应焓变为负值

B、升高温度,逆反应速率增大,正反应速率减小,反应逆向移动

C、不论增大压强还是减小压强,正方向速率改变的程度更大

D、平衡正向移动,NO的转化率一定增大

E、平衡体系中加入NO2,平衡逆向移动,△H2减小

F、混合气体颜色加深说明平衡向右移动,颜色变浅则向左移动.

同类题3

完形填空,先通读下面的短文,掌握其大意,然后在每小题所给的四个选项中,选出可以填入空白处的最佳选项。

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    Bollywood is not a physical place. Some people 3 the name, saying that it makes the industry look like a poor cousin to Hollywood.4 ,Bollywood is one of the largest centers of film production in the world.

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