如图所示的传统民居中，最适合游牧民族居住的是（  ）

    A new study says that American children have exciting after-school life. Many junior and senior students have a lot of interesting things to do in their free time. About 57% students have activities every day. 82% students have activities at least four times a week. American students spend their free time doing sports or enjoying arts, music and dancing. They like to have fun outside school because they can make a lot of friends during their activities.

合成氨工业的原料气H₂，可用天然气制取，其生产流程如图：

（1）写出反应I的反应方程式：____ 该反应的平衡常数表达式为：____ 　；

（2）转化炉中反应为：CO（g）+H₂O（g）⇌CO₂（g）+H₂（g），其平衡常数与温度关系如表：

该反应为：　放热　反应（填“吸热”或“放热”）．

（3）合成氨反应原理为：N₂（g）+3H₂（g）⇌2NH₃（g）△H=﹣92.4KJ/mol

回答下列问题：

①工业合成氨原料氮气制备方法是____ 

②在一定温度下，将1molN₂和3molH₂充入一容积不变的密闭容时器中进行合成反应，达到平衡时，容器的压强为起始的$\frac{4}{5}$，平衡状态记为S₀，则平衡时容器内NH₃的体积分数为____ ；若保持温度不变，开始时向容器加入a mol N₂，b mol H₂，c mol NH₃，要使反应始终向逆反应方向进行，且达到平衡后向各物质的理与原平衡S₀完全相同，则起始时c的取值范围应是____ ．