1.综合题- (共2题)
（1）火箭升空时，由于与大气层的剧烈摩擦，产生高温。为了防止火箭温度过高，在火箭一面涂上一种特殊的涂料，该涂料的性质最可能的是 。
| A．在高温下不融化 | B．在高温下可分解气化 |
| C．在常温下就分解气化 | D．该涂料不可能发生分解 |
（2）火箭升空需要高能的燃料，经常是用N2O4和N2H4和作为燃料，其反应的方程式是：N2O4+N2H4→N2+H2O。请配平该反应方程式： N2O4+ N2H4→ N2+ H2O
该反应中被氧化的原子与被还原的原子的物质的量之比是 。这个反应应用于火箭推进器，除释放大量的热和快速产生大量气体外，还有一个很大的优点是 。
（3）如图是某空间站能量转化系统的局部示意图，其中燃料电池采用KOH为电解液，燃料电池放电时的负极反应为： 。如果某段时间内氢氧储罐中共收集到33.6L气体（已折算成标况），则该段时间内水电解系统中转移电子的物质的量为 mol。
（4）在载人航天器的生态系统中，不仅要求分离去除CO2，还要求提供充足的O2。某种电化学装置可实现如下转化：2CO2=2CO+O2，CO可用作燃料。已知该反应的阳极反应为：4OH—4e-=O2↑+2H2O 则阴极反应为： 。有人提出，可以设计反应2CO=2C+O2（△H＞0、△S＜0）来消除CO的污染。请你判断上述反应是否能发生？ 理由 。
（5）.北京奥运会“祥云”火炬燃料是丙烷（C3H8），亚特兰大奥运会火炬燃料是丙烯(C3H6)。丙烷脱氢可得丙烯。
已知：①C3H8(g)
CH4(g)+HC≡CH(g)+H2(g)； △H1="156.6" kJ·mol-1②CH3CH=CH2(g)
CH4(g)+ HC≡CH (g)；△H2="32.4" kJ·mol-1则相同条件下，反应C3H8(g)
CH3CH=CH2(g)+H2(g)的△H=_____kJ·mol-1
⑴镓的基态原子的电子排布式是 。
⑵砷化镓晶胞中所包含的砷原子（白色球）个数为 ，与同一个镓原子相连的砷原子构成的空间构型为 。
⑶N、P、As处于同一主族，其氢化物沸点由高到低的顺序是 。（用氢化物分子式表示）
⑷砷化镓可由(CH3)3Ga和AsH3在700℃时制得。(CH3)3Ga中镓原子的杂化方式为 。
⑸比较二者的第一电离能：As______Ga（填“<”、“>”或“=”）。
⑹下列说法正确的是 （填字母）。
A．砷化镓晶胞结构与NaCl相同 B．GaP与GaAs互为等电子体
C．电负性：As>Ga D．砷化镓晶体中含有配位键
2.推断题- (共1题)
达菲和乐感清的结构简式如下图所示：
请回答下列问题：
（1）乐感清的分子式是____ 。
（2）合成达菲的主要原料莽草酸(结构简式为
)存在于我国盛产的八角茴香中。关于莽草酸性质的描述，下列说法正确的是（）A. 1 mol莽草酸与足量的金属钠反应可生成4mol H2。
B. 1 mol莽草酸与足量氢氧化钠溶液反应，最多可消耗氢氧化钠4 mol。
C. 1 mol莽草酸与足量的碳酸钠溶液反应可生成二氧化碳气体1 mol。
D. 1 mol莽草酸与足量的碳酸氢钠溶液反应可生成二氧化碳气体1 mol
（3）下列每组中各有三对物质，它们都能用分液漏斗分离的是
A．乙酸乙酯和水，酒精和水，植物油和水
B．四氯化碳和水，溴苯和水，硝基苯和水
C．甘油和水，乙酸和水，乙酸和乙醇
D．汽油和水，苯和水，乙二醇和水
Ⅱ.下图中A、B、C、D、E均为有机化合物。已知：C能跟NaHCO3溶液发生反应，C和D的相对分子质量相等，且E为无支链的化合物。请回答下列问题：
（1）C分子中官能团的名称是 ；化合物B不能发生的反应是 (填字母序号)。
a．加成反应 b．取代反应 c．消去反应
d．酯化反应 e．水解反应 f．氧化反应
（2）反应②的化学方程式是___________________________。（3） A的结构简式是_________________。
（4）同时符合下列三个条件的B的同分异构体的数目有______个。
a含有间二取代苯环结构 b.属于非芳香酸酯 c.可与FeCl3溶液发生显色反应
写出其中任意一个同分异构体的结构简式__________________________________。
3.选择题- (共6题)
阅读理解
Rosie Dutton, a teacher from Relax Kids in Tamworth, UK, used two apples to show her students the often unseen but harmful effects of school bullying(校园欺凌). She posted the lesson on Facebook, where it's been shared more than 160,000 times.
Rosie Dutton explained that during one of her classes she presented the children with two red apples. What the kids didn't know was that before the lesson, she had repeatedly dropped one of the apples on the floor. And yet, on the outside at least, both apples looked perfect.
“I picked up the apple I'd dropped on the floor and started to tell the children how I disliked this apple,” Dutton wrote. “I told them that because I didn't like it, I didn't want them to like it either, so they should call it names too.”Some of the children looked at her as if she were “crazy”, but the students passed the apple around the circle, calling it names.
Continuing the exercise, the teacher then passed the second apple around the circle. This apple, however, was showered with words like: “Your skin is beautiful,” and “ what a beautiful colour you have.”
Dutton then showed the students both apples once again, stressing that “there was no change, and both apples still looked the same.”
Finally, Dutton cut both apples open. The apple that the class treated kindly looked fresh inside. But the other apple—the one they'd treated poorly —was bruised（瘀伤的) beneath its skin.
“I think there was a light bulb moment for the children immediately,” Dutton said. “When people are bullied, especially children, they feel horrible inside and sometimes don't show or tell others how they are feeling. If we hadn't have cut that apple open, we would never have known how much pain we had caused it.”
Dutton explained how important it is to teach children to stand up for one another, and to stop any form of bullying.
“Let's create a generation of kind caring children,” the teacher wrote. “The tongue has no bones, but is strong enough to break a heart. So be careful with your words.”
阅读理解
Rosie Dutton, a teacher from Relax Kids in Tamworth, UK, used two apples to show her students the often unseen but harmful effects of school bullying(校园欺凌). She posted the lesson on Facebook, where it's been shared more than 160,000 times.
Rosie Dutton explained that during one of her classes she presented the children with two red apples. What the kids didn't know was that before the lesson, she had repeatedly dropped one of the apples on the floor. And yet, on the outside at least, both apples looked perfect.
“I picked up the apple I'd dropped on the floor and started to tell the children how I disliked this apple,” Dutton wrote. “I told them that because I didn't like it, I didn't want them to like it either, so they should call it names too.”Some of the children looked at her as if she were “crazy”, but the students passed the apple around the circle, calling it names.
Continuing the exercise, the teacher then passed the second apple around the circle. This apple, however, was showered with words like: “Your skin is beautiful,” and “ what a beautiful colour you have.”
Dutton then showed the students both apples once again, stressing that “there was no change, and both apples still looked the same.”
Finally, Dutton cut both apples open. The apple that the class treated kindly looked fresh inside. But the other apple—the one they'd treated poorly —was bruised（瘀伤的) beneath its skin.
“I think there was a light bulb moment for the children immediately,” Dutton said. “When people are bullied, especially children, they feel horrible inside and sometimes don't show or tell others how they are feeling. If we hadn't have cut that apple open, we would never have known how much pain we had caused it.”
Dutton explained how important it is to teach children to stand up for one another, and to stop any form of bullying.
“Let's create a generation of kind caring children,” the teacher wrote. “The tongue has no bones, but is strong enough to break a heart. So be careful with your words.”
4.单选题- (共2题)
①NH4H的电子式
②硝基苯的结构简式：
③葡萄糖的实验式：CH2O
④甲烷分子的比例模型：
⑤Fe2+的离子结构：
⑥原子核内有10个中子的氧原子：
⑦sp2杂化轨道模型：
| A．②③⑤ | B．①③⑤⑥ | C．③⑥⑦ | D．②③⑥⑦ |
| A．大力开发丰富的煤炭资源，减少对石油的依赖 |
| B．在西部和沿海地区兴建风力发电站，解决能源问题 |
| C．世博会很多场馆的外壳使用非晶硅薄膜，以充分利用太阳能，体现低碳经济 |
| D．世博停车场安装催化光解设施，可将汽车尾气中CO和NOx反应生成无毒气体 |
5.实验题- (共1题)
I．实验装置如下图所示（5分）
（1）硝酸铜固体加热分解的产物有氧化铜、二氧化氮和氧气。写出该反应的化学方程________________。
（2）当集气瓶中充满红棕色气体时，木条复燃了。有的同学得出“NO2能支持木条的燃烧”的结论。你认为这一结论是否正确？____________（填“正确”或“不正确”），理由是_______
II．实验装置如图所示：（5分）
（1）写出浓硝酸受热分解的化学方程式：__________________________________。（2分）
（2）实验开始后木条上的火星逐渐熄灭，有的同学提出“NO2不能支持木条的燃烧”的结论。你认为这一结论是否正确？________（填“正确”或“不正确”），理由是 。（3分）
III．为了更能直接说明“NO2能否支持木条的燃烧”这一问题，请你重新设计一个简单的实验方案，简述实验原理和主要操作。（2分）_________________________________________________。
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【1】题量占比
综合题:(2道)
推断题:(1道)
选择题:(6道)
单选题:(2道)
实验题:(1道)
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【2】：难度分析
1星难题：0
2星难题：0
3星难题：0
4星难题：0
5星难题：0
6星难题：5
7星难题：0
8星难题：0
9星难题：1