2014高考名师推荐化学选做题练习2

适用年级:高三
试卷号:293926

试卷类型:高考模拟
试卷考试时间:2017/7/26

1.推断题(共1题)

1.
可降解聚合物P的合成路线如下

(1)A的含氧官能团名称是____________。
(2)羧酸a的电离方程是________________。
(3)B→C的化学方程式是_____________。
(4)化合物D苯环上的一氯代物有2种,D的结构简式是___________。
(5)E→F中反应①和②的反应类型分别是___________。
(6)F的结构简式是_____________。
(7)聚合物P的结构简式是________________。

2.选择题(共5题)

2.完形填空

The Fitting-in of Suzy Khan

    The first time I saw Suzy Khan, I knew I had to help her. She was really small for her age of 12. The boy in my class often 1 about her and laughed their heads off. She would open a book, pretending to read, with tears dropping on the open page.

    All I knew was that she was an orphan (孤儿) from Africa. She had just been adopted by a family in town who 2 that the best way for her to learn American ways of life was to be with American kids. I looked down at this 3 girl and promised myself that somehow I would help her.

    But how could I help her 4 in with us? There had to be a 5 .

    One day, when I went into the classroom, I saw that Suzy had 6 her geography book to a picture of a train, and in her notebook, she had made a(n) 7copy.

    I was surprised and thought that she could do something in the coming 8 show. So, I took her to see the art teacher, Miss Parker, and showed her what Suzy had 9. “Why, it's wonderful,” said Miss Parker, who then showed us a poster she had painted 10 the talent show. “I need more of these, but I just don't have enough  11. Could you help me, Suzy?”

    On the day of the talent show, Suzy's 12 were everywhere ---- all over the hall and all over the school, each one different.

     “And finally,” said Mr Brown, the schoolmaster, at the end of the show, “we have a (n) award. I'm sure you've all noticed the wonderful posters.” Everyone nodded. “One of our own students 13 them.”

    I could hear everyone whispering. “Who in our school could draw 14 well?”

    Mr. Brown waited a while before saying, “ 15 this student worked so hard on the posters, she deserves a 16 ,too. Our mystery(神秘) artist is our new student 17 Suzy Khan!”

    Mr. Brown thanked her for all the wonderful posters and gave her a professional artist's set. “Thank you,” she cried.

    I 18 , at that time when I was looking at her excited face, she'd probably never 19 anything in her whole life.

    Everyone started to 20 their hands. Suzy Khan gave them a shy smile and the applause was defining. I knew then Suzy was going to be all right.

3.阅读理解

Multitasking

    What is the first thing you notice when you walk into a shop? The products displayed (展示) at the entrance? Or the soft background music?

    But have you ever notice the smell? Unless it is bad, the answer is likely to be no. But while a shop's scent may not be outstanding compared with sights and sounds, it is certainly there. And it is providing to be an increasing powerful tool in encouraging people to purchase.

    A brand store has become famous for its distinctive scent which floats through the fairly dark hall and out to the entrance, via scent machines. A smell may be attractive but it may not just be used for freshening air. One sports goods company once reported that when it first introduced scent into its stores, customers' intension to purchase increased by 80 percent.

    When it comes to the best shopping streets in Pairs, scent is just as important to a brand's success as the quality of its window displays and goods on sales. That is mainly because shopping is a very different experience to what it used to be.

    Some years ago, the focus for brand name shopping was on a few people with sales assistants' disproving attitude and don't touch what you can't afford displays. Now the rise of electronic commerce (e-commerce) has opened up famous brands to a wider audience. But while e-shops can use sights and sounds, only bricks-and-mortar stores (实体店) can offer a full experience from the minute customers step through the door to the moment they leave. Another brand store seeks to be much more than a shop, but rather a destination. And scent is just one way to achieve this. Now a famous store uses complex man-made smell to make sure that the soft scent of baby powder floats through the kid department, and coconut (椰子) scent in the swimsuit section. A department store has even opened a new lab, inviting customers on a journey into the store's windows to smell books, pots and drawers, in search of their perfect scent.

4.阅读理解

Multitasking

    What is the first thing you notice when you walk into a shop? The products displayed (展示) at the entrance? Or the soft background music?

    But have you ever notice the smell? Unless it is bad, the answer is likely to be no. But while a shop's scent may not be outstanding compared with sights and sounds, it is certainly there. And it is providing to be an increasing powerful tool in encouraging people to purchase.

    A brand store has become famous for its distinctive scent which floats through the fairly dark hall and out to the entrance, via scent machines. A smell may be attractive but it may not just be used for freshening air. One sports goods company once reported that when it first introduced scent into its stores, customers' intension to purchase increased by 80 percent.

    When it comes to the best shopping streets in Pairs, scent is just as important to a brand's success as the quality of its window displays and goods on sales. That is mainly because shopping is a very different experience to what it used to be.

    Some years ago, the focus for brand name shopping was on a few people with sales assistants' disproving attitude and don't touch what you can't afford displays. Now the rise of electronic commerce (e-commerce) has opened up famous brands to a wider audience. But while e-shops can use sights and sounds, only bricks-and-mortar stores (实体店) can offer a full experience from the minute customers step through the door to the moment they leave. Another brand store seeks to be much more than a shop, but rather a destination. And scent is just one way to achieve this. Now a famous store uses complex man-made smell to make sure that the soft scent of baby powder floats through the kid department, and coconut (椰子) scent in the swimsuit section. A department store has even opened a new lab, inviting customers on a journey into the store's windows to smell books, pots and drawers, in search of their perfect scent.

5.阅读理解

Sea Life Melbourne Aquarium (水族馆)

    The all-new Sea Life Melbourne Aquarium, situated in the heart of Melbourne's CBD, is one of Victoria's leading visitor attractions and an unforgettable outing for the whole family. Having 12 amazing zones of discovery, Sea Life Melbourne Aquarium is the very place that you cannot miss when you visit the city.

    * Opening Times

    Sea Life Melbourne Aquarium is open from 9:30 am until 6:00 pm every day of the year, including public holidays. Last admission is at 5:00 pm, one hour before closing.

    * Location ( 位置)

    Sea Life Melbourne Aquarium is located on the corner of Flinders Street and King Street, Melbourne. It is siyuated on the Yarra River, opposite Crown Entertainment Complex.

    * Getting to Sea Life Melbourne Aquarium

    Train

    The Sea Life Melbourne Aquarium train stop is located on the free City Circle Tram route (公交线路) and also routes 70 and 75. City Circle trams run every 10 minutes in both directions.

    Shuttle Bus

    The Sea Life Melbourne Aquarium is a free bus service, stopping at key tourist attractions in and around the City. Running daily, every 15 minutes from 10:00 am to 4:00 pm.

    Car Parking

    While there is no public car parking at Sea Life Melbourne Aquarium, there are several public car parking lots available only a short walk away.

    * Wheelchair Access

    Sea Life Melbourne Aquarium provides people in wheelchairs with full access to all 12 zones. Each floor also has wheelchair accessible toilets.

    * Terms

    Tickets will be emailed to you immediately after purchase or you can download and print your ticket once payment has been accepted. Please print out all tickets purchased and present at the front entrance of Sea Life Melbourne Aquarium. No ticket, no entry!

6.阅读理解

Sea Life Melbourne Aquarium (水族馆)

    The all-new Sea Life Melbourne Aquarium, situated in the heart of Melbourne's CBD, is one of Victoria's leading visitor attractions and an unforgettable outing for the whole family. Having 12 amazing zones of discovery, Sea Life Melbourne Aquarium is the very place that you cannot miss when you visit the city.

    * Opening Times

    Sea Life Melbourne Aquarium is open from 9:30 am until 6:00 pm every day of the year, including public holidays. Last admission is at 5:00 pm, one hour before closing.

    * Location ( 位置)

    Sea Life Melbourne Aquarium is located on the corner of Flinders Street and King Street, Melbourne. It is siyuated on the Yarra River, opposite Crown Entertainment Complex.

    * Getting to Sea Life Melbourne Aquarium

    Train

    The Sea Life Melbourne Aquarium train stop is located on the free City Circle Tram route (公交线路) and also routes 70 and 75. City Circle trams run every 10 minutes in both directions.

    Shuttle Bus

    The Sea Life Melbourne Aquarium is a free bus service, stopping at key tourist attractions in and around the City. Running daily, every 15 minutes from 10:00 am to 4:00 pm.

    Car Parking

    While there is no public car parking at Sea Life Melbourne Aquarium, there are several public car parking lots available only a short walk away.

    * Wheelchair Access

    Sea Life Melbourne Aquarium provides people in wheelchairs with full access to all 12 zones. Each floor also has wheelchair accessible toilets.

    * Terms

    Tickets will be emailed to you immediately after purchase or you can download and print your ticket once payment has been accepted. Please print out all tickets purchased and present at the front entrance of Sea Life Melbourne Aquarium. No ticket, no entry!

3.填空题(共3题)

7.
请回答下列问题:
(1)N、Al、Si、Zn四种元素中,有一种元素的电离能数据如下:
电离能 I1 I2I3I4
In/kJ.mol-1 【小题1】1817 2745 11578 …
 
则该元素是   (填写元素符号)。
(2)基态锗(Ge)原子的电子排布式是  ,Ge的最高价氯化物分子式是    ,该元素可能的性质或应用有
A.是一种活泼的金属元素 B.其电负性大于硫
C.其单质可作为半导体材料  D.其最高价氯化物的沸点低于其溴化物的沸点
(3)关于化合物,下列叙述正确的有
A.分子间可形成氢键  
B.分子中既有极性键又有非极性键
C.分子中有7个σ键和1个π键
D.该分子在水中的溶解度大于2-丁烯
(4)NaF的熔点 的熔点(填>、=或<),其原因是    
8.
废旧锂离子池的正极材料(主要含有LiCoO2及少量的Al、Fe等)可用于回收钴、锂,工艺流程如下:

(1)在上述溶解过程中,S2O32-被氧化成SO42-,LiCoO2在溶解过程中发生反应的化学方程式为 ,还原产物是
(2)在上述除杂过程中,通入空气的作用是 废渣的主要成分是    
(3)“沉淀钴”和“沉淀锂”的离子方程式分别为
(4)除了废渣可以回收利用外,本工艺还可回收的副产品是     
9.
硅在地壳中的含量较高。硅及其化合物的开发由来已久,在现代生活中有广泛应用。回答下列问题:
(1)1810年瑞典化学家贝采利乌斯在加热石英砂、木炭和铁时,得到一种“金属”。这种“金属”可能是
(2)陶瓷、水泥和玻璃是常用的硅酸盐材料。其中,生产普通玻璃的主要原料有    
(3)高纯硅是现代信息、半导体和光伏发电等产业都需要的基础材料。工业上提纯硅有多种路线,其中一种工艺流程示意图及主要反应如下:

①用石英砂和焦炭在电弧炉中高温加热也可以生产碳化硅,该反应的化学方程式为    ;碳化硅又称 ,其晶体结构与 相似。
②在流化床反应的产物中,SiHCl3大约占85%,还有SiCl4、SiH2Cl2、SiH3Cl等,有关物质的沸点数据如下表,提纯SiHCl3的主要工艺操作依次是沉降、冷凝和    
物质
Si
SiCl4
SiHCl3
SiH2Cl2
SiH3Cl
HCl
SiH4
沸点/℃
2355
57.6
31.8
8.2
-30.4
-84.9
-111.9
 
③SiHCl3极易水解,其完全水解的产物为
(4)氯碱工业可为上述工艺生产提供部分原料,这些原料是
试卷分析
  • 【1】题量占比

    推断题:(1道)

    选择题:(5道)

    填空题:(3道)

  • 【2】:难度分析

    1星难题:0

    2星难题:0

    3星难题:0

    4星难题:0

    5星难题:0

    6星难题:4

    7星难题:0

    8星难题:0

    9星难题:0